A sample of argon gas is trapped in a long glass tube with a drop of mercury acting as a movable lid. The length (y, measured in cm) of this gas column (which of course is proportional to the volume of argon) is measure at various temperatures (x, in °C). The accuracy of the length measurement is 0.1 cm.
In 1787 Jacques Charles claimed that the volume of a gas held at constant pressure depended linearly on temperature:
V = V0(1 + T/T0)
where V0 is the volume of the gas at T=0 and we now interpret T = -T0 as the lowest possible temperature: absolute zero. (Note [contrary to fact] that if the argon remained in gaseous form at T=-T0, it would have V=0; which, of course, is impossible.)
In this experiment, volume is proportional to length so we can translate Charles' Law as:
L = L0(1 + T/T0)
where L0 is the length of the gas at T=0 etc. If we compare this law to the generic equation for a line, we find:
A = L0
B = L0/T0
so
T0 = A/B
X (°C) | Y (cm) |
---|---|
-6 | 24.6 |
9 | 25.7 |
35 | 28.1 |
38 | 28.4 |
65 | 31.0 |
71 | 31.5 |
81 | 32.4 |
89 | 33.1 |
95 | 33.8 |
99 | 34.0 |